If the pressure shifting effect is significant it would be particularly bad for the 384cm-1 setting used for Betelgeuse and Antares, since I used very strong lines to set the wn zeropoint.
To investigate the magnitude of the effect, I took spectra of water lines using the laboratory gas cell.
I set up EXES for HIGH_MEDIUM, 384 cm-1, 2nd order, with the 1.9" slit. Then I took a number of spectra with different fill pressures in the gas cell. The water content was supplied by ambient vapor in the room that doesn't get swept out by the scroll pump. I added dry pressure with N2 from a spent cryogen tank.
Here's what the undistorted sky spectrum from observations on Antares during F198 looked like.
And here are a couple of spectra of the gas cell at different pressures.
And then I reduced them to 1-d spectra
And measured the width and wavenumbers of the strong lines, using the same fitting tool as I use for wavelength calibrating all piped spectra.
There is a clear linear trend between FWHM and wavenumber -- [Sorry, the units and y-axis are mislabeled. Should be "Central wavenumber (cm-1").]
The width of the real sky line data in F198 is shown with the vertical magenta line. If the gas cell lines at their narrowest represent the true rest wavenumber from HITRAN, then using the positions of the sky telluric lines would induce a spurious blueshift of 1-2 km/s, by my estimation.
I also measured the weak H2O line at 383.510 cm-1. It was present in the sky data and the lower pressure gas cell data. It doesn't appear to have the same linear trend. Does that mean I can trust its HITRAN value? The fits to the higher pressure gas cell spectra were not very robust due to the small line strength next to similar scale spectral fringing.










